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The removal of impurities from a process stream
Author(s)
Himmelstutzer, E.A.
Date Issued
2002
Type
Thesis
Publisher
Cape Technikon
Abstract
The high purity 1-octene produced by Sasol Alpha Olefins in Secunda and
which is sold to DOW Chemical Company for co-monomer application, has
performed poorly over the DOW Ziegler-Natta catalysts. The reason for the
poor performance was catalyst poisoning caused by low-level impurities
present in the 1-octene. Much work from Sasol and DOW has gone into
identifying the components responsible for catalyst deactivation, as well as
methods suitable for removing them without significant 1-octene losses.
Super NMP (n-Methyl-2-Pyrrolidone) extractive distillation piloting was
performed previously on 1-octene in order to remove the low-level impurities
that deactivate the DOW catalysts.
VLE (vapour liquid equilibrium) test work performed previously indicated that
all xylenol isomers are more promising as extractive distillation solvents than
NMP.
which is sold to DOW Chemical Company for co-monomer application, has
performed poorly over the DOW Ziegler-Natta catalysts. The reason for the
poor performance was catalyst poisoning caused by low-level impurities
present in the 1-octene. Much work from Sasol and DOW has gone into
identifying the components responsible for catalyst deactivation, as well as
methods suitable for removing them without significant 1-octene losses.
Super NMP (n-Methyl-2-Pyrrolidone) extractive distillation piloting was
performed previously on 1-octene in order to remove the low-level impurities
that deactivate the DOW catalysts.
VLE (vapour liquid equilibrium) test work performed previously indicated that
all xylenol isomers are more promising as extractive distillation solvents than
NMP.
Additional information
Thesis (MTech (Chemical Engineering))--Cape Technikon, 2002.
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8002102_Hidmmelstutzer_EA_Mtech_Mechanical_Eng_Eng_2002_8002102.pdf
Description
Thesis
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32.42 MB
Format
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